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dc.contributor.authorMartínez Reina, Marlon Doney
dc.contributor.authorAmado González, Eliseo
dc.date.accessioned2020-01-08T19:04:36Z
dc.date.available2020-01-08T19:04:36Z
dc.date.issued2011-12-01
dc.identifierhttps://revistas.unimilitar.edu.co/index.php/rcin/article/view/258
dc.identifier10.18359/rcin.258
dc.identifier.urihttp://hdl.handle.net/10654/33105
dc.descriptionThe excess molar volumes of 30 binary mixtures containing ionic liquids of imidazolium with different molecular solvents: (methanol, ethanol, propan-1-ol, propan-2-ol, acetone, 2- butanone, 2-pentanone, methyl acetate, ethyl acetate, butyl acetate, dimethyl carbonate, diethyl carbonate, nitromethane, 1,3-dichloropropane and ethylene glycol), were predicted from the refractive index data, using three types of methods coupled with several different mixing rules for refractive index calculations: Lorentz-Lorenz, Dale-Gladstone, Eykman, Arago-Biot, Newton and Oster. In these systems, molecular interactions and intermolecular forces during mixing produce positive or negative deviations from ideal behavior. The results are analyzed in terms of the nature of ionic liquid and molecular solvent.eng
dc.descriptionEl volumen de exceso molar de 30 mezclas binarias que contienen líquidos iónicos de imidazolio con diferentes solventes moleculares: (metanol, etanol, 1-propanol, 2-propanol, acetona, 2- butanona, 2-pentanona, acetato de metilo, acetato de etilo, acetato de butilo, carbonato de dimetilo, carbonato de dietilo, nitrometano, 1,3-dicloropropano y etilenglicol),se predice desde datos de índice de refracción, usando tres tipos de métodos acoplados con diferentes reglas de mezcla para el cálculo del índice de refracción: Lorentz-Lorenz, Dale-Gladstone, Eykman, Arago- Biot, Newton y Oster. En estos sistemas, las interacciones moleculares y las fuerzas intermoleculares provocan, durante la mezcla, desviaciones positivas o negativas del comportamiento ideal. Los resultados obtenidos se analizan en términos de la naturaleza del líquido iónico y solvente molecular.spa
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dc.language.isospa
dc.publisherUniversidad Militar Nueva Granadaspa
dc.rightsDerechos de autor 2016 Ciencia e Ingeniería Neogranadinaspa
dc.rightshttps://creativecommons.org/licenses/by-nc-nd/4.0spa
dc.sourceCiencia e Ingenieria Neogranadina; Vol 21 No 2 (2011); 21-40eng
dc.sourceCiencia e Ingeniería Neogranadina; Vol. 21 Núm. 2 (2011); 21-40spa
dc.sourceCiencia e Ingeniería Neogranadina; v. 21 n. 2 (2011); 21-40por
dc.source1909-7735
dc.source0124-8170
dc.titleBinary mixtures of ionic liquid with molecular solvent: Prediction of excess molar volumes from refractive indexeng
dc.titleMezclas binarias de líquido iónico con solvente molecular: Predicción del volumen de exceso molar desde índices de refracciónspa
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dc.subject.proposalExcess molar volumeeng
dc.subject.proposalrefractive indexeng
dc.subject.proposalpredictioneng
dc.subject.proposalliquid ioniceng
dc.subject.proposalmolecular solvent.eng
dc.subject.proposalvolumen de exceso molarspa
dc.subject.proposalíndice de refracciónspa
dc.subject.proposalpredicciónspa
dc.subject.proposallíquido iónicospa
dc.subject.proposalsolvente molecularspa


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