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dc.creatorMartínez Reina, Marlon Doney
dc.creatorAmado González, Eliseo
dc.date2011-12-01
dc.identifierhttps://revistas.unimilitar.edu.co/index.php/rcin/article/view/258
dc.identifier10.18359/rcin.258
dc.descriptionThe excess molar volumes of 30 binary mixtures containing ionic liquids of imidazolium with different molecular solvents: (methanol, ethanol, propan-1-ol, propan-2-ol, acetone, 2- butanone, 2-pentanone, methyl acetate, ethyl acetate, butyl acetate, dimethyl carbonate, diethyl carbonate, nitromethane, 1,3-dichloropropane and ethylene glycol), were predicted from the refractive index data, using three types of methods coupled with several different mixing rules for refractive index calculations: Lorentz-Lorenz, Dale-Gladstone, Eykman, Arago-Biot, Newton and Oster. In these systems, molecular interactions and intermolecular forces during mixing produce positive or negative deviations from ideal behavior. The results are analyzed in terms of the nature of ionic liquid and molecular solvent.en-US
dc.descriptionEl volumen de exceso molar de 30 mezclas binarias que contienen líquidos iónicos de imidazolio con diferentes solventes moleculares: (metanol, etanol, 1-propanol, 2-propanol, acetona, 2- butanona, 2-pentanona, acetato de metilo, acetato de etilo, acetato de butilo, carbonato de dimetilo, carbonato de dietilo, nitrometano, 1,3-dicloropropano y etilenglicol),se predice desde datos de índice de refracción, usando tres tipos de métodos acoplados con diferentes reglas de mezcla para el cálculo del índice de refracción: Lorentz-Lorenz, Dale-Gladstone, Eykman, Arago- Biot, Newton y Oster. En estos sistemas, las interacciones moleculares y las fuerzas intermoleculares provocan, durante la mezcla, desviaciones positivas o negativas del comportamiento ideal. Los resultados obtenidos se analizan en términos de la naturaleza del líquido iónico y solvente molecular.es-ES
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dc.publisherUniversidad Militar Nueva Granadaes-ES
dc.relationhttps://revistas.unimilitar.edu.co/index.php/rcin/article/view/258/68
dc.relationhttps://revistas.unimilitar.edu.co/index.php/rcin/article/view/258/1896
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dc.rightsDerechos de autor 2016 Ciencia e Ingeniería Neogranadinaes-ES
dc.sourceCiencia e Ingenieria Neogranadina; Vol. 21 No. 2 (2011); 21-40en-US
dc.sourceCiencia e Ingeniería Neogranadina; Vol. 21 Núm. 2 (2011); 21-40es-ES
dc.sourceCiencia e Ingeniería Neogranadina; v. 21 n. 2 (2011); 21-40pt-BR
dc.source1909-7735
dc.source0124-8170
dc.subjectExcess molar volumeen-US
dc.subjectrefractive indexen-US
dc.subjectpredictionen-US
dc.subjectliquid ionicen-US
dc.subjectmolecular solvent.en-US
dc.subjectvolumen de exceso molares-ES
dc.subjectíndice de refracciónes-ES
dc.subjectpredicciónes-ES
dc.subjectlíquido iónicoes-ES
dc.subjectsolvente moleculares-ES
dc.titleBinary mixtures of ionic liquid with molecular solvent: Prediction of excess molar volumes from refractive indexen-US
dc.titleMezclas binarias de líquido iónico con solvente molecular: Predicción del volumen de exceso molar desde índices de refracciónes-ES
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/publishedVersion


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