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Mezclas binarias de líquido iónico con solvente molecular: Predicción del volumen de exceso molar desde índices de refracción
dc.creator | Martínez Reina, Marlon Doney | |
dc.creator | Amado González, Eliseo | |
dc.date | 2011-12-01 | |
dc.identifier | https://revistas.unimilitar.edu.co/index.php/rcin/article/view/258 | |
dc.identifier | 10.18359/rcin.258 | |
dc.description | The excess molar volumes of 30 binary mixtures containing ionic liquids of imidazolium with different molecular solvents: (methanol, ethanol, propan-1-ol, propan-2-ol, acetone, 2- butanone, 2-pentanone, methyl acetate, ethyl acetate, butyl acetate, dimethyl carbonate, diethyl carbonate, nitromethane, 1,3-dichloropropane and ethylene glycol), were predicted from the refractive index data, using three types of methods coupled with several different mixing rules for refractive index calculations: Lorentz-Lorenz, Dale-Gladstone, Eykman, Arago-Biot, Newton and Oster. In these systems, molecular interactions and intermolecular forces during mixing produce positive or negative deviations from ideal behavior. The results are analyzed in terms of the nature of ionic liquid and molecular solvent. | en-US |
dc.description | El volumen de exceso molar de 30 mezclas binarias que contienen líquidos iónicos de imidazolio con diferentes solventes moleculares: (metanol, etanol, 1-propanol, 2-propanol, acetona, 2- butanona, 2-pentanona, acetato de metilo, acetato de etilo, acetato de butilo, carbonato de dimetilo, carbonato de dietilo, nitrometano, 1,3-dicloropropano y etilenglicol),se predice desde datos de índice de refracción, usando tres tipos de métodos acoplados con diferentes reglas de mezcla para el cálculo del índice de refracción: Lorentz-Lorenz, Dale-Gladstone, Eykman, Arago- Biot, Newton y Oster. En estos sistemas, las interacciones moleculares y las fuerzas intermoleculares provocan, durante la mezcla, desviaciones positivas o negativas del comportamiento ideal. Los resultados obtenidos se analizan en términos de la naturaleza del líquido iónico y solvente molecular. | es-ES |
dc.format | application/pdf | |
dc.format | text/html | |
dc.language | spa | |
dc.publisher | Universidad Militar Nueva Granada | es-ES |
dc.relation | https://revistas.unimilitar.edu.co/index.php/rcin/article/view/258/68 | |
dc.relation | https://revistas.unimilitar.edu.co/index.php/rcin/article/view/258/1896 | |
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dc.rights | Derechos de autor 2016 Ciencia e Ingeniería Neogranadina | es-ES |
dc.source | Ciencia e Ingenieria Neogranadina; Vol. 21 No. 2 (2011); 21-40 | en-US |
dc.source | Ciencia e Ingeniería Neogranadina; Vol. 21 Núm. 2 (2011); 21-40 | es-ES |
dc.source | Ciencia e Ingeniería Neogranadina; v. 21 n. 2 (2011); 21-40 | pt-BR |
dc.source | 1909-7735 | |
dc.source | 0124-8170 | |
dc.subject | Excess molar volume | en-US |
dc.subject | refractive index | en-US |
dc.subject | prediction | en-US |
dc.subject | liquid ionic | en-US |
dc.subject | molecular solvent. | en-US |
dc.subject | volumen de exceso molar | es-ES |
dc.subject | índice de refracción | es-ES |
dc.subject | predicción | es-ES |
dc.subject | líquido iónico | es-ES |
dc.subject | solvente molecular | es-ES |
dc.title | Binary mixtures of ionic liquid with molecular solvent: Prediction of excess molar volumes from refractive index | en-US |
dc.title | Mezclas binarias de líquido iónico con solvente molecular: Predicción del volumen de exceso molar desde índices de refracción | es-ES |
dc.type | info:eu-repo/semantics/article | |
dc.type | info:eu-repo/semantics/publishedVersion |
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